Mise En Surbrillance Des Boutton Visual Studio (WPF .net)

Dans ton fichier MainWindow.xaml il faut modifier la couleur au niveau de la propriété Button.MouseOver.Background du style par défaut :

<Window x:Class="MNS_WPF.MainWindow"
        xmlns="http://schemas.microsoft.com/winfx/2006/xaml/presentation"
        xmlns:x="http://schemas.microsoft.com/winfx/2006/xaml"
        xmlns:d="http://schemas.microsoft.com/expression/blend/2008"
        xmlns:mc="http://schemas.openxmlformats.org/markup-compatibility/2006"
        xmlns:local="clr-namespace:MNS_WPF"
        mc:Ignorable="d"
        Title="MainWindow" Height="450" Width="800">
    <Window.Resources>
        <Style x:Key="FocusVisual">
            <Setter Property="Control.Template">
                <Setter.Value>
                    <ControlTemplate>
                        <Rectangle Margin="2" StrokeDashArray="1 2" Stroke="{DynamicResource {x:Static SystemColors.ControlTextBrushKey}}" SnapsToDevicePixels="true" StrokeThickness="1"/>
                    </ControlTemplate>
                </Setter.Value>
            </Setter>
        </Style>
        <SolidColorBrush x:Key="Button.Static.Background" Color="#FFDDDDDD"/>
        <SolidColorBrush x:Key="Button.Static.Border" Color="#FF707070"/>
        <SolidColorBrush x:Key="Button.MouseOver.Background" Color="#FFd33434"/>
        <SolidColorBrush x:Key="Button.MouseOver.Border" Color="#FF3C7FB1"/>
        <SolidColorBrush x:Key="Button.Pressed.Background" Color="#FFC4E5F6"/>
        <SolidColorBrush x:Key="Button.Pressed.Border" Color="#FF2C628B"/>
        <SolidColorBrush x:Key="Button.Disabled.Background" Color="#FFF4F4F4"/>
        <SolidColorBrush x:Key="Button.Disabled.Border" Color="#FFADB2B5"/>
        <SolidColorBrush x:Key="Button.Disabled.Foreground" Color="#FF838383"/>
        <Style x:Key="ButtonStyle1" TargetType="{x:Type Button}">
            <Setter Property="FocusVisualStyle" Value="{StaticResource FocusVisual}"/>
            <Setter Property="Background" Value="{StaticResource Button.Static.Background}"/>
            <Setter Property="BorderBrush" Value="{StaticResource Button.Static.Border}"/>
            <Setter Property="Foreground" Value="{DynamicResource {x:Static SystemColors.ControlTextBrushKey}}"/>
            <Setter Property="BorderThickness" Value="1"/>
            <Setter Property="HorizontalContentAlignment" Value="Center"/>
            <Setter Property="VerticalContentAlignment" Value="Center"/>
            <Setter Property="Padding" Value="1"/>
            <Setter Property="Template">
                <Setter.Value>
                    <ControlTemplate TargetType="{x:Type Button}">
                        <Border x:Name="border" Background="{TemplateBinding Background}" BorderBrush="{TemplateBinding BorderBrush}" BorderThickness="{TemplateBinding BorderThickness}" SnapsToDevicePixels="true">
                            <ContentPresenter x:Name="contentPresenter" Focusable="False" HorizontalAlignment="{TemplateBinding HorizontalContentAlignment}" Margin="{TemplateBinding Padding}" RecognizesAccessKey="True" SnapsToDevicePixels="{TemplateBinding SnapsToDevicePixels}" VerticalAlignment="{TemplateBinding VerticalContentAlignment}"/>
                        </Border>
                        <ControlTemplate.Triggers>
                            <Trigger Property="IsDefaulted" Value="true">
                                <Setter Property="BorderBrush" TargetName="border" Value="{DynamicResource {x:Static SystemColors.HighlightBrushKey}}"/>
                            </Trigger>
                            <Trigger Property="IsMouseOver" Value="true">
                                <Setter Property="Background" TargetName="border" Value="{StaticResource Button.MouseOver.Background}"/>
                                <Setter Property="BorderBrush" TargetName="border" Value="{StaticResource Button.MouseOver.Border}"/>
                            </Trigger>
                            <Trigger Property="IsPressed" Value="true">
                                <Setter Property="Background" TargetName="border" Value="{StaticResource Button.Pressed.Background}"/>
                                <Setter Property="BorderBrush" TargetName="border" Value="{StaticResource Button.Pressed.Border}"/>
                            </Trigger>
                            <Trigger Property="IsEnabled" Value="false">
                                <Setter Property="Background" TargetName="border" Value="{StaticResource Button.Disabled.Background}"/>
                                <Setter Property="BorderBrush" TargetName="border" Value="{StaticResource Button.Disabled.Border}"/>
                                <Setter Property="TextElement.Foreground" TargetName="contentPresenter" Value="{StaticResource Button.Disabled.Foreground}"/>
                            </Trigger>
                        </ControlTemplate.Triggers>
                    </ControlTemplate>
                </Setter.Value>
            </Setter>
        </Style>
    </Window.Resources>
    <Grid>
        <Grid.RowDefinitions>
            <RowDefinition Height="0*"/>
            <RowDefinition/>
        </Grid.RowDefinitions>
        <Button Style="{DynamicResource ButtonStyle1}" x:Name="bouton1" Content="Button" HorizontalAlignment="Left" Margin="135,73,0,0" VerticalAlignment="Top" Height="65" Width="265" Background="#FF3D43E2" Grid.RowSpan="2"/>

    </Grid>
</Window>

Tu dois changer la couleur au niveau de la ligne 21.

Attention si tu copies-colles ce code, il faudra adapter le nom de ton bouton et le nom du namespace.